Benzene-1,3-diammonium bis(pyridine-2,6-dicarboxylato)nickelate(II) pentahydrate
نویسندگان
چکیده
In the title compound, (C(6)H(10)N(2))[Ni(C(7)H(3)NO(4))(2)]·5H(2)O, the Ni(II) ion is six-coordinated by two N and four O atoms from two pyridine-2,6-dicarboxyl-ate ligands in a distorted octa-hedral fashion. The crystal packing is stabilized by inter-molecular O-H⋯O and N-H⋯O and weak C-H⋯O hydrogen bonds and π-π inter-actions [centroid-centroid distances = 3.4669 (19) and 3.764 (2) Å].
منابع مشابه
Benzene-1,3-diammonium bis(pyridine-2,6-dicarboxylato-κ3 O 2,N,O 6)cobaltate(II) pentahydrate
In the title compound, (C(6)H(10)N(2))[Co(C(7)H(3)NO(4))(2)]·5H(2)O, the Co(II) ion is six-coordinated in an N(2)O(4) environment by two pyridine-2,6-dicarboxyl-ate (pydc) ligands, having a distorted octa-hedral geometry. The crystal packing is stabilized by inter-molecular N-H⋯O, O-H⋯O and weak C-H⋯O hydrogen bonds. There are also π-π inter-actions between the pyridine rings of the pydc ligand...
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متن کامل(Propane-1,3-diammonium) bis(4-hydroxypyridine-2,6-dicarboxylato-κ3 O 2,N,O 6)zinc(II) 3.5-hydrate
The asymmetric unit of the title compound, (C(3)H(12)N(2))[Zn(C(7)H(3)NO(5))(2)]·3.5H(2)O, contains two formula units. The compound consists of an anionic complex, a doubly protonated propane-1,3-diamine as a counter-ion and 3.5 uncoord-inated water mol-ecules. The coordination polyhedron around the Zn(II )atom is distorted octa-hedral, defined by four O atoms and two N atoms from two Hchel (H(...
متن کاملPoly[(μ3-benzene-1,3-dicarboxylato-κ4 O 1:O 1′:O 3,O 3′)bis(pyridine-κN)cobalt(II)]
In the asymmetric unit of the title polymeric compound, [Co(C(8)H(4)O(4))(C(5)H(5)N)(2)](n), there are two crystallographically independent Co(II) atoms, each of which is six-coordinated in a distorted octa-hedral geometry by four O atoms from benzene-dicarboxyl-ate anions and two N atoms from pyridine ligands. The benzene-dicarboxyl-ate dianions bridge the Co(II) atoms into a tape running alon...
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011